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- BACKVALL, JE, et al.
(author)
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STEREOCHEMISTRY AND MECHANISM OF CHLOROPALLADATION OF ACETYLENES
- 1995
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In: ORGANOMETALLICS. - : AMER CHEMICAL SOC. ; 14:9
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Other publication (other academic/artistic)abstract
- The stereochemistry of chloropalladation of acetylenes has been studied. Chloropalladation adducts from terminal acetylenes were trapped in situ by reaction with either allyl chloride or 1,3-cyclohexadiene. It was found that the stereochemistry of the ch
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2. |
- Gatti, RGP, et al.
(author)
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Palladium-catalysed enantiodivergent synthesis of cis- and trans-4-aminocyclohex-2-enols
- 1997
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In: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1. - : ROYAL SOC CHEMISTRY. ; :4
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Other publication (other academic/artistic)abstract
- Enantiomerically pure cis- and trans-4-aminocyclohex-2-enols are prepared from cyclohexa-1,3-diene via (-)-cis-(1R,4S)-4-acetoxycyclohex-2-enol(-)-2a using palladium(0) chemistry, Benzylamine and diethylamine are tested in the Pd-0-catalysed allylic amin
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3. |
- Larsson, ALE, et al.
(author)
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Synthesis of chiral and achiral analogues of ambroxol via palladium-catalysed reactions
- 1997
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In: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1. - : ROYAL SOC CHEMISTRY. ; :19
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Other publication (other academic/artistic)abstract
- Chiral cis-and trans-4-aminocyclohex-2-enols and achiral 4-aminocyclohexanols, which all are analogues of ambroxol, are prepared via stereoselective allylic substitution of cyclohex-2-ene-1,4-diol derivatives or 1-acetoxy-4-chlorocyclohex-2-ene. The chir
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